Usually issues of that nature are the result of some structural movement in the house, such as foundation settlement, wood shrinkage, or excessive deflection of structural members such as joists or beams. I suppose it's also possible that the door frames were not properly shimmed when they were installed, and a frame has perhaps become bent, but this is unlikely.
Exactly how much daylight can you see above the door? Is the gap a constant width, or is it wider where the two doors meet, and narrower at the side? Or does it taper the other way, wider at the side than in the middle? Is the gap over just one of the pair of doors, or both?
If the gap is tapered and very small, like from one-eighth of an inch to zero, perhaps a hinge can be shimmed to align the door. This is done by removing the hinge from the door frame and cutting a piece of cardboard the shape of the hinge, and punching holes in the cardboard where the screws will go. Then you re-install the hinge with the cardboard behind it. Depending on the width of the gap, you may need more than one piece of cardboard, and depending on the direction of the taper (if the gap is indeed tapered) you will do this to either the top hinge or the bottom one.
But, first check for any small structural movement, using a carpenter's level. Check the floor at the door opening, check both door jambs, check the door head, check the walls adjacent to the door. The level may reveal the cause of the problem.
Architect (NY) and Home Designer (PA)